Product Name: p-Resorcinol
Chemical Name: 1,3-Dihydroxybenzene
Synonyms: Resorcinol, Benzene-1,3-diol
Chemical Formula: C6H6O2
CAS Number: 108-46-3
Recommended Use: Dyes, analytical reagent, pharmaceuticals, resins, cosmetics
Manufacturer: Supplied by chemical manufacturers and distributors, contact details on label or invoice
Emergency Phone: Listed on the product shipping document or supplier website
Hazard Classification: Eye and skin irritant, hazardous to aquatic environment, acute toxicity if swallowed
GHS Label Elements: Signal word Danger, hazard pictograms for health hazard, exclamation mark, environmental hazard
Hazard Statements: Harmful if swallowed, causes serious eye damage, may cause skin irritation, toxic to aquatic organisms
Precautionary Statements: Avoid release to environment, wear protective clothing, wash hands thoroughly after handling, do not eat/drink during use
Symptoms of Exposure: Burning eyes, skin redness, nausea, abdominal pain, headache, eye watering
Chemical Name: 1,3-Dihydroxybenzene
CAS Number: 108-46-3
Concentration: Typically ≥98%
Impurities: Trace phenolic compounds, water (low percentage possible depending on grade)
Additives: None reported for most technical and reagent grades
Inhalation: Remove person to fresh air, keep comfortable, provide oxygen if breathing is difficult, get medical help if symptoms persist
Skin Contact: Rinse with plenty of water for 15 minutes, remove contaminated clothing, wash with mild soap, seek medical attention if irritation continues
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses, continue rinsing, get immediate medical advice
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical attention or call Poison Center
Suitable Extinguishing Media: Water spray, dry powder, CO2, foam; avoid direct water jet
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, irritating vapors
Special Protective Equipment: Firefighters should use self-contained breathing apparatus, chemical-resistant suit
Advice for Firefighters: Keep containers cool, dike fire-control water for later disposal, evacuate area if necessary
Explosion Risk: Dust can form explosive mixtures with air; handle material away from ignition sources
Personal Precautions: Evacuate area, avoid breathing dust, ventilate area, wear gloves, goggles, protective clothing
Environmental Precautions: Prevent entry to sewers and waterways, notify authorities if significant spill occurs
Methods for Cleaning Up: Collect spilled material with non-sparking tools, use inert absorbent, store in closed containers, sweep up carefully to avoid dust
Decontamination: Wash spill area with plenty of soap and water, ventilate area after cleanup
Safe Handling Advice: Handle in well-ventilated area, minimize dust formation, avoid contact with eyes, skin, and clothing, do not breathe dust
Hygiene Practices: Wash hands after handling, keep food and drinks away from work zone, launder contaminated clothing
Storage Requirements: Store in tightly closed containers in cool, dry place, away from oxidizers, acids, heat sources, sunlight, and moisture
Incompatibilities: Strong oxidizing agents, acids, bases, some metals
Occupational Exposure Limits: ACGIH TLV: 10 mg/m³ (inhalable fraction and vapor), NIOSH REL: 10 mg/m³
Engineering Controls: Local exhaust ventilation, process enclosure, mechanical ventilation
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), splash goggles, lab coat, in case of dust mask or respirator certified for particulates
Workplace Practices: Keep eyewash stations and safety showers accessible, avoid direct contact with material, do not eat/drink/smoke in workplace
Appearance: White to faintly pink, needle-like crystals
Odor: Faintly sweet, phenolic odor
Molecular Weight: 110.11 g/mol
Melting Point: 110-112 °C
Boiling Point: 277 °C
Flash Point: 127 °C (closed cup)
Solubility: Soluble in water, ethanol, ether
pH: Acidic in solution
Vapor Pressure: Low at room temperature
Partition Coefficient (log Kow): 0.8
Decomposition Temperature: Not readily available; decomposes at elevated temperature
Autoignition Temperature: 520 °C
Explosive Properties: Dust explosion risk in enclosed spaces
Oxidizing Properties: Not classified as oxidizer
Chemical Stability: Stable at recommended storage and use conditions
Reactivity: May react with strong oxidizing agents and acids
Hazardous Reactions: Exothermic reactions possible with incompatible substances, releases irritating and toxic gases on thermal decomposition
Conditions to Avoid: Excess heat, sparks, open flame, moisture, incompatible materials
Incompatible Materials: Strong acids, oxidizers, bases, metals including alkali metals
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, phenolic compouds and vapors
Acute Toxicity: Oral LD50 (rat): 301 mg/kg
Inhalation: May cause respiratory tract irritation, headache, dizziness
Skin Contact: Causes skin irritation, allergic reaction possible on contact
Eye Contact: Causes serious eye irritation and risk of permanent damage with concentrated exposure
Chronic Exposure: Prolonged or repeated contact can cause dermatitis, sensitization, effects on nervous system
Carcinogenicity: Not classified as carcinogen by IARC, NTP, or OSHA
Mutagenicity: Negative in standard genetic toxicity tests
Other Data: May cause methemoglobinemia, hemolysis of red blood cells (especially in high exposure)
Aquatic Toxicity: Toxic to aquatic life, LC50 (fish): 34 mg/L/96h (Oncorhynchus mykiss)
Environmental Fate: Biodegradable under aerobic conditions, may persist in anaerobic environments
Bioaccumulation Potential: Low, based on log Kow
Mobility in Soil: Mobile in moist soil, can leach to groundwater
Effects on Microorganisms: Toxic at high concentrations, may inhibit microbial activity in water and soil
Other Information: Prevent contamination of surface and ground water
Waste Disposal Methods: Collect and store contaminated material in containers suitable for chemical waste, transfer to licensed hazardous waste disposal facility
Contaminated Packaging: Triple rinse and dispose as hazardous waste, return to vendor for recycling if possible
Regulatory Considerations: Comply with local, state, and national hazardous waste and environmental protection regulations
Other Notes: Do not dump into the environment or municipal sewage
UN Number: 2876
UN Proper Shipping Name: Resorcinol
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: III
Environmental Hazards: Toxic to aquatic organisms, mark accordingly if required
Special Precautions for Transport: Secure containers tightly, protect from moisture, ensure documentation meets transport authority requirements
Regulation Reference: ADR/RID, IMDG, IATA guidelines
OSHA Status: Hazardous chemical under OSHA Hazard Communication Standard
TSCA Inventory: Listed
SARA Title III Sections 302/313: Not listed as extremely hazardous, not subject to reporting as toxic chemical, but check local rules
REACH Status (EU): Registered, subject to supply chain safety and communication requirements
Labeling Requirements: GHS hazard pictograms, signal word Danger, risk and safety phrases as specified by jurisdiction
Other Regulatory Approvals: Complies with requirements of country-specific chemical control regulations worldwide
