Boxa Chemical Group Ltd
Knowledge

Material Safety Data Sheet: Nonylphenol

1. Identification

Product Name: Nonylphenol
Chemical Formula: C15H24O
CAS Number: 25154-52-3
Relevant Identified Uses: Intermediate in chemical manufacturing, nonionic surfactant production, plastic additives, antioxidant in lubricants, emulsifier in agriculture
Manufacturer: Provided on supplier invoice or packaging
Emergency Phone: Listed on manufacturer or supplier MSDS

2. Hazard Identification

GHS Classification: Acute Toxicity (Oral) - Category 4; Skin Corrosion/Irritation - Category 2; Serious Eye Damage/Irritation - Category 2A; Hazardous to Aquatic Environment (Acute) - Category 1; Hazardous to Aquatic Environment (Chronic) - Category 1
Pictograms: Exclamation Mark, Corrosion, Environment
Signal Word: Danger
Hazard Statements: Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life with long lasting effects.
Precautionary Statements: Avoid contact with skin and eyes. Do not breathe dust, fumes, gas, mist, vapors, spray. Wash thoroughly after handling.

3. Composition / Information on Ingredients

Chemical Name: Nonylphenol
Synonyms: 4-Nonylphenol, p-Nonylphenol
Concentration: ≥ 95% by weight
Impurities: Trace amounts of related alkylphenols, water (≤ 1%)

4. First Aid Measures

Inhalation: Move to fresh air. If breathing becomes difficult, seek medical attention. Remove from exposure, monitor for respiratory distress.
Skin Contact: Remove contaminated clothing. Wash affected skin thoroughly with soap and water. If irritation develops and persists, consult a healthcare professional.
Eye Contact: Rinse eyes gently with plenty of water for several minutes. Remove contact lenses if easy to do. Continue rinsing. Get medical advice if irritation occurs.
Ingestion: Rinse mouth. Do not induce vomiting. Drink water if conscious. Call poison control or seek immediate medical help if symptoms appear.

5. Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, CO2, foam, or water spray.
Unsuitable Extinguishing Media: Direct water stream may scatter liquid, risk of fire spread.
Specific Hazards: Combustion produces carbon monoxide, carbon dioxide, toxic organic vapors.
Protective Equipment: Wear self-contained breathing apparatus and full protective gear.
Additional Advice: Keep containers cool by spraying with water to prevent rupture.

6. Accidental Release Measures

Personal Precautions: Evacuate area if necessary. Wear appropriate gloves, goggles, and chemical resistant clothing. Ventilate area to avoid vapor buildup.
Environmental Precautions: Prevent entry into soil, ditches, sewers, waterways. Nonylphenol can cause irreversible damage to aquatic systems.
Methods for Cleanup: Use absorbent materials such as sand or vermiculite. Shovel into approved chemical waste containers. Wash spill site with plenty of water but prevent runoff into natural water bodies.

7. Handling and Storage

Handling: Wear gloves, goggles, and protective clothing. Use chemically resistant containers and equipment. Avoid creating aerosols or breathing vapors. Practice good industrial hygiene.
Storage Conditions: Store tightly closed in cool, dry, well-ventilated area away from heat, sparks, open flames, alkaline substances, and strong oxidizers. Keep away from foodstuffs and animal feed.
Incompatible Materials: Strong acids, oxidizing agents, bases

8. Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust ventilation to minimize vapor exposure. Work outdoors or in a chemical fume hood when possible.
Exposure Limits: No established OSHA or ACGIH exposure limits exist for nonylphenol; minimize exposure based on risk assessments and regulations.
Personal Protective Equipment: Wear chemical-resistant gloves (nitrile recommended), safety goggles or face shield, long-sleeved clothing, and, for large-scale use, respiratory protection such as an organic vapor respirator.
Hygiene Measures: Wash hands thoroughly after handling. Remove and wash contaminated clothing before reuse.

9. Physical and Chemical Properties

Appearance: Colorless to pale yellow, viscous liquid, sometimes waxy solid at room temperature
Odor: Slight aromatic
Melting Point: Approximately 30°C (86°F)
Boiling Point: 293°C (559°F)
Flash Point: 150°C (302°F)
Solubility: Insoluble in water; miscible with most organic solvents
Density: About 0.95 to 0.98 g/cm³
Vapor Pressure: Very low at ambient temperature
pH: Not applicable (neutral compound)

10. Stability and Reactivity

Chemical Stability: Stable under normal temperatures and conditions.
Reactivity: May react with strong oxidizing agents, strong acids, and bases.
Hazardous Decomposition: Produces irritating and toxic vapors such as carbon monoxide and various phenolic compounds upon combustion.
Polymerization: Does not occur under recommended handling and storage conditions.

11. Toxicological Information

Acute Effects: Harmful if swallowed, inhaled, or absorbed through skin; causes skin and eye irritation.
Chronic Effects: Suspected endocrine disruptor in animals and humans; may impact reproductive hormones and development with prolonged exposure.
Symptoms: Nausea, vomiting, headache, skin redness or rash, eye discomfort.
LD50 (oral, rat): Approximately 580 mg/kg
Carcinogenicity: Not classified by IARC, NTP, or OSHA as a known human carcinogen.
Other Risks: Prolonged or repeated exposure can cause dermatitis.

12. Ecological Information

Ecotoxicity: Highly toxic to aquatic organisms, causes long-term adverse effects in the aquatic environment.
Bioaccumulation: Tends to bioaccumulate in aquatic organisms; significant concentrations found in fish tissue.
Degradability: Slowly biodegradable in water and soil; persistent in sediments.
Mobility in Soil: Potential for limited mobility; adsorbs strongly to sediment and organic matter.

13. Disposal Considerations

Waste Disposal Method: Incinerate or dispose at approved hazardous waste facilities; follow all local, state, and federal requirements.
Disposal of Contaminated Packaging: Rinse containers, then send for industrial disposal or recycling as hazardous waste.
Precautions: Avoid release to environment during disposal; do not flush to sewer.

14. Transport Information

UN Number: UN3082
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Nonylphenol)
Hazard Class: 9 (Miscellaneous hazardous material)
Packing Group: III
Marine Pollutant: Yes
Special Precautions: Use secure containers, label and document in line with current transport regulations for hazardous chemicals.
Transport Regulations: ADR/RID, IMDG, IATA comply with international shipment standards.

15. Regulatory Information

OSHA: Regulated as a hazardous chemical under OSHA Hazard Communication Standard.
TSCA: Listed on the Toxic Substances Control Act Inventory.
SARA Section 313: Nonylphenol may be subject to reporting under SARA Title III.
REACH: Registered substance within the European Union; subject to use restrictions.
Other State/Local: State and local regulations may apply more stringent controls.