Boxa Chemical Group Ltd
Knowledge

Material Safety Data Sheet (MSDS) for Dodecylphenol

Identification

Product Name: Dodecylphenol
Chemical Family: Alkylphenol
Synonyms: C12-phenol; 4-dodecylphenol
CAS Number: 123-31-9
Recommended Use: Intermediate in chemical synthesis, surfactant precursor, lubricant additive
Supplier: Check chemical label for manufacturer details
Emergency Contact: Refer to local regulations or supplier guidelines
UN Number: 3082 (Environmentally hazardous substance, liquid, n.o.s.)

Hazard Identification

GHS Classification: Acute Toxicity (oral, dermal, inhalation), Eye Irritation, Skin Irritation, Chronic Aquatic Hazard
Label Elements: Danger, corrosive, environmental hazard pictogram
Hazard Statements: Causes severe skin burns and eye damage, harmful if swallowed, toxic to aquatic life with long lasting effects
Signal Word: Danger
Precautionary Statements: Avoid breathing vapors, wear protective gloves and eye protection, prevent release to environment, wash thoroughly after handling.

Composition / Information on Ingredients

Chemical Identity: 4-Dodecylphenol
Concentration: ≥97% (may vary by manufacturer)
Impurities: Other alkylphenols (<2%), water (<1%)
EC Number: 204-393-1
Molecular Formula: C18H30O

First Aid Measures

Inhalation: Move to fresh air, maintain open airway, provide oxygen if breathing is difficult, seek medical attention
Skin Contact: Remove contaminated clothing, rinse skin with water and soap for at least 15 minutes, get medical help for persistent irritation or burns
Eye Contact: Rinse with plenty of water for several minutes, remove contact lenses, continue rinsing and call a doctor
Ingestion: Rinse mouth, do not induce vomiting, immediately contact a poison center or physician
Symptoms: Burning pain, redness, blistering, respiratory irritation, eye or skin damage

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray
Unsuitable Media: Direct water jets may spread fire
Special Hazards: Emits toxic fumes, including carbon monoxide and carbon dioxide, under fire conditions
Special Protection: Firefighters should use self-contained breathing apparatus (SCBA) and chemical protective clothing
Additional: Cool containers with water, avoid contamination of watercourses

Accidental Release Measures

Personal Precautions: Wear chemical-resistant gloves, eye protection, avoid inhalation of vapors
Environmental Precautions: Prevent product from entering drains or waterways, report spills to authorities as required
Containment: Stop leak if without risk, dike to prevent entry into water or soil
Cleanup Methods: Absorb with sand or inert material, place in suitable chemical waste container, ventilate area, wash spill site after material removal

Handling and Storage

Safe Handling: Use only in well-ventilated areas, avoid contact with skin and eyes, do not breathe fumes or mist, keep containers tightly closed
Storage Conditions: Store in cool, dry, well-ventilated place away from heat or ignition sources, keep away from food and drink, use appropriate containment to avoid environmental contamination
Incompatible Materials: Strong acids, bases, oxidizing agents, halogens
Additional: Use proper grounding and bonding for bulk transfers to avoid static discharge

Exposure Controls and Personal Protection

Exposure Limits: No established workplace exposure limit; minimize airborne concentrations
Engineering Controls: Local exhaust ventilation, eyewash stations, safety showers
Personal Protective Equipment: Chemical safety goggles, face shield, neoprene or nitrile gloves, chemical-resistant clothing, rubber boots
Respiratory Protection: Use approved respirators if engineering controls are inadequate
Hygiene Measures: Wash hands after handling, remove and wash contaminated clothing, avoid eating or drinking near chemical use

Physical and Chemical Properties

Appearance: Clear to pale yellow viscous liquid
Odor: Phenolic, slightly pungent
Boiling Point: Around 330°C (626°F)
Melting Point: Typically below 10°C (50°F)
Flash Point: About 140°C (284°F) (closed cup)
Solubility: Insoluble in water, soluble in many organic solvents
Density: Approximately 0.9 g/cm³
Vapor Pressure: Low at room temperature
pH: Not applicable (not water soluble)
Partition Coefficient (log Kow): High (estimated >5), tends to bioaccumulate

Stability and Reactivity

Chemical Stability: Stable under normal conditions of storage and handling
Conditions to Avoid: Prolonged exposure to strong heat, sources of ignition, moisture
Incompatible Materials: Strong oxidizing agents, acids, bases
Decomposition Products: Carbon monoxide, carbon dioxide, phenolic derivatives
Hazardous Polymerization: Not expected under recommended conditions

Toxicological Information

Acute Toxicity: Oral LD50 rat: ~2000 mg/kg, can be harmful if swallowed
Skin Corrosion/Irritation: Causes burns and blistering on contact
Serious Eye Damage: Severe irritation, risk of permanent injury
Respiratory Sensitization: Inhalation of mist may irritate or burn mucous membranes
Carcinogenicity: Not listed as carcinogenic by IARC, ACGIH, NTP, OSHA
Reproductive Toxicity: No established data, avoid exposure
Additional Effects: Liver or kidney effects possible after repeated exposure

Ecological Information

Aquatic Toxicity: Highly toxic to aquatic organisms, risk of long-term adverse effects in aquatic environment
Persistence and Degradability: Sluggish biodegradation; can remain in environment for extended periods
Bioaccumulation Potential: Expected to bioaccumulate based on high log Kow
Mobility in Soil: Adsorbs strongly to soil/sediment, low mobility
Other Adverse Effects: Persistent environmental contaminant, notify local environmental authorities in event of release

Disposal Considerations

Waste Treatment Methods: Handle as hazardous waste, incineration preferred with appropriate flue gas treatment
Contaminated Packaging: Triple rinse and dispose according to local, regional, national regulations
Disposal Precautions: Prevent release into sewers or the environment, contact licensed waste disposal service

Transport Information

UN Number: 3082
UN Proper Shipping Name: Environmentally Hazardous Substance, Liquid, N.O.S. (contains dodecylphenol)
Transport Hazard Class: 9 (Miscellaneous dangerous substances and articles)
Packing Group: III
Marine Pollutant: Yes
Special Transport Precautions: Ensure proper labeling, use secure and sealed containers, comply with relevant transportation headings for hazardous materials

Regulatory Information

US TSCA Inventory: Listed
Canadian DSL: Listed
EU REACH Registration: Required, substance of very high concern (SVHC) for some uses
Labeling Requirements: Comply with OSHA Hazard Communication Standard, GHS
Other Regulation: Subject to restriction under environmental protection and chemical safety laws, seek local regulations for workplace and environmental exposure compliance