Boxa Chemical Group Ltd
Knowledge

Material Safety Data Sheet: 2,6-Bis(Hydroxymethyl)-P-Cresol

Identification

Product Name: 2,6-Bis(Hydroxymethyl)-P-Cresol
Chemical Formula: C9H12O3
Synonyms: 4-Methyl-2,6-bis(hydroxymethyl)phenol, TMCP
CAS Number: 700-13-0
Recommended Uses: Intermediate for resins, plasticizers, stabilizers
Supplier: Contact supplier for name and phone number
Emergency Contact: Refer to local regulations for emergency phone

Hazard Identification

Classification: Irritant for eyes and skin; harmful if inhaled or ingested
Signal Word: Warning
Pictograms: Exclamation mark
Hazard Statements: Causes skin and serious eye irritation, may cause respiratory irritation. Can be harmful if swallowed. Prolonged or repeated exposure may lead to allergic reactions.
Precautionary Statements: Avoid contact with skin and eyes, use appropriate protective gear, keep container tightly closed, work in well-ventilated spaces.

Composition / Information on Ingredients

Chemical Identity: 2,6-Bis(Hydroxymethyl)-P-Cresol
Concentration: ≥ 99% by weight
Impurities: Residuals from synthesis below 1% total; none classified as hazardous
Molecular Weight: 168.19 g/mol

First Aid Measures

Inhalation: Move to fresh air. If symptoms persist, seek medical attention. Give oxygen if breathing becomes difficult.
Skin Contact: Remove contaminated clothing. Wash skin thoroughly with soap and water. Seek medical care if irritation remains.
Eye Contact: Rinse eyes for at least 15 minutes using clean water, lifting upper and lower eyelids frequently. Contact an ophthalmologist.
Ingestion: Rinse mouth. Drink water to dilute. Avoid inducing vomiting. Contact medical services immediately.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Straight water jets
Hazards from Combustion: May give off carbon monoxide, carbon dioxide, and toxic fumes under fire conditions
Protective Equipment: Firefighters should use self-contained breathing apparatus, chemical-resistant clothing, and gloves
Special Procedures: Remove containers from fire area if safe, cool surfaces with water spray, avoid inhalation of smoke

Accidental Release Measures

Personal Precautions: Wear gloves, goggles, and suitable protective clothing. Keep people away from the area, ventilate space.
Environmental Precautions: Prevent discharge into drains, water sources, or soil. Notify authorities if a large spill threatens the environment.
Cleanup Methods: Absorb small spills with inert material (sand, earth). For large spills, use nonsparking tools and place into secure containers. Dispose of waste in line with local regulations.
Decontamination: Wash area with industrial detergent and copious water, avoid spreading material

Handling and Storage

Handling: Use in well-ventilated areas, avoid inhaling dust or vapor. Wear proper PPE including gloves, goggles, and protective clothing. Avoid eating or drinking nearby.
Storage: Store in tightly sealed, labeled containers in a cool, dry, well-ventilated place. Keep away from incompatible materials such as strong oxidizers and acids. Protect from direct sunlight and moisture. Keep away from sources of ignition.

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limit established, monitor airborne concentrations
Engineering Controls: Use local exhaust ventilation, enclosed processes to reduce exposure
Respiratory Protection: Wear an approved respirator when handling dust or vapor, especially in unventilated spaces
Hand Protection: Wear chemical-resistant gloves (nitrile, neoprene)
Eye Protection: Use safety glasses with side shields or full-face visor
Skin Protection: Wear lab coat, overalls, or chemical apron
Hygiene Measures: Wash hands thoroughly after handling, remove contaminated clothing before eating or drinking

Physical and Chemical Properties

Appearance: White to pale yellow crystalline powder
Odor: Faint aromatic
Odor Threshold: Not established
pH: Not available in aqueous solution
Melting Point: 111 – 113 °C
Boiling Point: Decomposes before boiling
Flash Point: >180 °C (closed cup)
Flammability: Not classified as flammable solid
Vapor Pressure: Very low at 20 °C
Solubility: Slightly soluble in water, soluble in most organic solvents
Density: 1.24 g/cm³
Partition Coefficient (n-octanol/water): Not available
Auto-ignition Temperature: Not established
Decomposition Temperature: >200 °C
Viscosity: Not applicable to solid
Evaporation Rate: Not applicable to solid

Stability and Reactivity

Chemical Stability: Stable at normal temperatures and pressure, but may degrade on exposure to heat
Reactivity: Not reactive under recommended storage and handling
Conditions to Avoid: Exposure to excessive heat, sources of ignition, strong sunlight
Incompatible Materials: Strong oxidizing agents, strong acids, strong bases
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, other toxic gases possible if product burns or decomposes
Polymerization: Hazardous polymerization will not occur

Toxicological Information

Acute Toxicity: Oral LD50 (rat): >2000 mg/kg, no severe toxicity reported at low doses
Skin Irritation: May cause dermatitis or redness after prolonged contact
Eye Irritation: Causes significant irritation, possible conjunctivitis
Respiratory Effects: Dust may cause irritation of nose, throat, and upper respiratory tract
Skin Sensitization: No clear evidence of sensitization in animal studies
Carcinogenicity: Not listed as carcinogen by IARC, NTP, OSHA
Mutagenicity: No evidence found
Reproductive Toxicity: No available information, insufficient testing on reproductive effects

Ecological Information

Aquatic Toxicity: Not acutely toxic to aquatic organisms at low concentrations, but avoid release to waterways
Persistence and Degradability: Expected to undergo slow biodegradation
Bioaccumulation Potential: Low—evidence suggests minimal accumulation in aquatic species
Mobility in Soil: Limited mobility due to low solubility in water
Other Adverse Effects: No ozone depletion, global warming, or photochemical smog effects associated with normal waste handling

Disposal Considerations

Waste Treatment Methods: Collect and place in containers suitable for chemical waste. Incinerate in certified facility if possible
Disposal of Contaminated Packaging: Triple rinse and dispose as chemical waste
Environmental Precautions: Do not dump into sewers, on the ground, or into bodies of water
Disposal Regulations: Follow all local, regional, and national regulations for chemical disposal

Transport Information

UN Number: Not regulated for ground, sea, or air transport
Proper Shipping Name: Not assigned
Transport Hazard Class: None
Packing Group: None
Marine Pollutant: Material not classified as marine pollutant
Special Precautions: Prevent spills, keep in tightly closed original container, secure against physical damage

Regulatory Information

OSHA Hazard Communication: Product supplied with SDS, follow label guidance
TSCA (USA): Listed
EINECS (EU): Listed under inventory
REACH Registration: Exempt or registered; consult supplier
WHMIS (Canada): Not classified as hazardous under current criteria
Other Regulations: Check local requirements for environmental, health, and fire hazards associated with storage, handling, and disposal of chemical products